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Table 2.

Flavonoid aglycones in Achillea crithmifolia

W. et K.

—---------

Substances

Samles

1

2

3

4

5

Pirdop - Cooper melting factory

+ + +

+

+ + + + +

+ + +

Sofia - „Tzarigradsko shousse“

+ + +

+

+ +

+ + + + + +

Vitosha - Platoto

+ + +

+

+ +

+ +

+ + +

Legend:

1 - apigenin; 2 - 6,7-dimethoxy-6-hydroxyluteolin; 3 - 3,4'-dimethoxykaempferol;

4-3,6,4'-trimethoxy-6-hydroxykaempferol; 5 - 3,6,4'-trimethoxyquercetagetin.

Quantity: + + + high; + + normal; + traces; - deficient

The synthesis of flavonoid aglycones in

Achillea crithmifolia

is higher in

samples taken from districts with transport (Sofia - Tzarigradsko shosse) and

industrial (Pirdop - Copper melting factory) pollution, and there is a reduced

synthesis in the sample with background pollution (Vitosha). In this case the

protective effect of flavonoids is proved ( И в а н ч е в а и

др .,

1998).

Table 3.

Flavonoid aglycones in Tanacetum vulgare

L.

Substances

Samples

1

2

3

4

5

6

Pirdop - Copper melting factory

-

-

-

+ + + + + +

Sofia - Tzarigradsko shosse

+ + + + + + + + + + + + + + + + +

Vitosha - Platoto

+

+ +

+ + + + + + + + + + +

Legend:

1 - 6,4'-dimethoxyscutellarein; 2 - Luteolin; 3 - 6-methoxy-6-hydroxyluteolin; 4 -

6,3'-dimethoxy-6-hydroxyluteolin; 5 - 3,6-dimethoxyquercetagetin 6. 3,6,3'-trimethoxyquercetagetin.

Quantity: + + + high; + + normal; + traces; - deficient

According to Table 3, 6,4'-dimethoxyscutellarein is in norm in the sample

with transport pollution. There are traces in the background polluted sample

and none in the industrial polluted sample. Luteolin and 6-methoxy-6-

hydroxyluteolin are present in high quantity in the region with transport

pollution, they are in norm in the background polluted sample, and lack in the

industrial polluted sample. 6,3'-dimethoxy-6-hydroxyluteolin, 3,6-dimethoxy­

quercetagetin and 3,6,3'-trimethoxyquercetagetin are in high quantity in the

samples with transport and background pollution, and lack in the other.

The synthesis of flavonoid aglycones in

Tanacetum vulgare

is higher in the

district with transport pollution, following by the sample with background

pollution and the synthesis is the lowest in the industrial pollution.

Table 4 shows that the quantity of flavonoids in

Achillea crithmifolia

is

higher in the sample with industrial pollution (0.1218 %), and lowest- in the

sample with transport pollution (0.0860 %). According to the quantity of

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